Today one of my myths was broken.
I used to believe that unordered_map is better in time-complexity than map in C++. But today while I was doing a problem(Molly's Chemicals), I got time-limit exceeded. After a lot of guess-work(because I thought my solution was correct), I tried using a map instead of an unordered_map and as a surprise I got it accepted. Then I realised that though the amortised time-complexity of using an unordered_map is O(1) while that of a map is O(log n), there are cases in which due to a lot of collisions unordered_map can have a big constant multiplier which will increase its actual complexity to greater than that of a map.
(Any corrections are welcomed...)

Can someone enlighten me more by clearing the doubt that where should unordered_map be used and where not?
What are the cases in which a map would perform better than an unordered_map?

Here are the tle and aced solution links if someone wants to verify:
TLE Solution(TLE after 2500 ms)
Accepted Solution(Accepted in 499 ms)